Process for isolation of cardanol from technical cashew (Anacardium occidentale L.) nut shell liquid

被引:188
作者
Kumar, PP [1 ]
Paramashivappa, R [1 ]
Vithayathil, PJ [1 ]
Rao, PVS [1 ]
Rao, AS [1 ]
机构
[1] Vittal Mallya Sci Res Fdn, Bangalore 560004, Karnataka, India
关键词
anacardic acid; cardol; cardanol; cashew nut shell liquid; Anacardium occidentale L;
D O I
10.1021/jf020224w
中图分类号
S [农业科学];
学科分类号
09 [农学];
摘要
Commercially available technical cashew (Anacardium occidentale L.) nut shell liquid (CNSL) contains mainly cardanol (decarboxylated anacardic acid) and cardol. Cardanol, the monophenolic component of technical CNSL, is widely used as a synthon for the preparation of a number of polymers and agricultural products. This paper describes the separation of cardanol from toxic cardol. Technical CNSL was dissolved in a mixture of methanol and ammonium hydroxide (8:5) and extracted with hexane to obtain cardanol. The resultant methanolic ammonia layer was extracted with a mixture of ethyl acetate and hexane to yield cardol. This is the first industrially-feasible process based on solvent extractions for the isolation of cardanol from technical CNSL.
引用
收藏
页码:4705 / 4708
页数:4
相关论文
共 14 条
[1]
[Anonymous], [No title captured]
[2]
*CASH EXP PROM COU, 1978, CASH NUT SHELL LIQ E
[3]
GEDAM PH, 1972, INDIAN J CHEM, V10, P388
[4]
INHIBITION OF LIPOXYGENASE AND PROSTAGLANDIN ENDOPEROXIDE SYNTHASE BY ANACARDIC ACIDS [J].
GRAZZINI, R ;
HESK, D ;
HEININGER, E ;
HILDENBRANDT, G ;
REDDY, CC ;
COXFOSTER, D ;
MEDFORD, J ;
CRAIG, R ;
MUMMA, RO .
BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1991, 176 (02) :775-780
[5]
GULATI AS, 1964, INDIAN J CHEM, V2, P114
[6]
KNOP W, 1979, CHEM APPL PHENOLIC R, V3
[7]
STRUCTURE ANTIBACTERIAL ACTIVITY RELATIONSHIPS OF ANACARDIC ACIDS [J].
KUBO, I ;
MUROI, H ;
HIMEJIMA, M ;
YAMAGIWA, Y ;
MERA, H ;
TOKUSHIMA, K ;
OHTA, S ;
KAMIKAWA, T .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1993, 41 (06) :1016-1019
[8]
MENON ARR, 1985, J SCI IND RES INDIA, V44, P324
[9]
Novel method for isolation of major phenolic constituents from cashew (Anacardium occidentale L.) nut shell liquid [J].
Paramashivappa, R ;
Kumar, PP ;
Vithayathil, PJ ;
Rao, AS .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2001, 49 (05) :2548-2551
[10]
PILLAI CKS, 1980, RRLM2729 MAT DIV