trans-(μ-5,5′-diethynyl-2,2′-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]

被引：3

作者：

Khan, MS

Al-Suti, MK

Ahrens, B

Raithby, PR

Teat, SJ

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Sultan Qaboos Univ, Coll Sci, Dept Chem, Al Khoud 123, Oman

[3] SERC, Daresbury Lab, CCLRC, Warrington WA4 4AD, Cheshire, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804010359

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Pt-2(C6H5)(2)(C14H6N2)(C6H15P)(4)], is a dinuclear Pt-II di-yne complex that exhibits pi-conjugation along the molecular backbone. It is used as a model complex for rigid-rod platinum poly-yne polymers of which it is a precursor. Such compounds are of interest because of the extended pi-conjugation through the aromatic/heteroaromatic spacer group in the backbone. The asymmetric unit contains two half molecules of the title compound, each lying on a crystallographic centre of symmetry situated at the mid-point of the central C - C bond of the bipyridine unit.

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页码：M735 / M737

页数：3

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