A Mo(VI) alkylidyne complex with polyhedral oligomeric silsesquioxane ligands: Homogeneous analogue of a silica-supported alkyne metathesis catalyst

被引：68

作者：

Cho, Hyeon Mo ^{[1
]}

Weissman, Haim ^{[1
]}

Wilson, Scott R. ^{[1
]}

Moore, Jeffrey S. ^{[1
]}

机构：

[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 46期

关键词：

D O I：

10.1021/ja065101x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly active alkyne metathesis catalyst is realized by replacing the amide ligands of a molybdenum(VI) trisamide alkylidyne complex with silanol groups from incompletely condensed POSS (polyhedral oligomeric silsesquioxane) ligands. This catalyst serves as an effective homogeneous mimic of an amorphous silica-supported catalyst. Reactivities of various catalytic mixtures are reported along with an X-ray structure of the aniline-coordinated amidodisiloxymolybdenum(VI) alkylidyne complex. Copyright © 2006 American Chemical Society.

引用

页码：14742 / 14743

页数：2

共 26 条

[1]

Abbenhuis HCL, 2000, CHEM-EUR J, V6, P25, DOI 10.1002/(SICI)1521-3765(20000103)6:1<25::AID-CHEM25>3.3.CO

[2]

2-P

[3]

Ballard D.G.H., 1973, ADV CATAL, P263

[4] Increased activity of in situ catalysts for alkyne metathesis [J].