Synthesis of novel group 4 metallocene-containing silsesquioxanes with a vinyl group

被引：23

作者：

Wada, K ^{[1
]}

Bundo, M ^{[1
]}

Nakabayashi, D ^{[1
]}

Itayama, N ^{[1
]}

Kondo, T ^{[1
]}

Mitsudoh, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 06期

关键词：

D O I：

10.1246/cl.2000.628

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel zirconocene or hafnocene-containing silsesquioxanes with a vinyl group Cp2M{[(vinyl)Me2Si](c-C5H9)(7)Si7O12} (Cp = cyclopentadienyl, M = Zr, Hf) were synthesized, as well as a derivative with a trimethylsilyl group Cp2Zr[(Me3Si)(c-C5H9)(7)Si7O12]. A derivative containing a dimethylethoxysilyl group was also synthesized.

引用

页码：628 / 629

页数：2

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