Mn2 bis(pentalene):: a mixed-spin bimetallic with two extremes of bonding within the same molecule

被引：34

作者：

Balazs, Gabor

Cloke, F. Geoffrey N.

Harrison, Andrew

Hitchcock, Peter B.

Green, Jennifer

Summerscales, Owen T.

机构：

[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England

[2] Univ Sussex, Dept Chem, Sch Life Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 08期

关键词：

D O I：

10.1039/b614765h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural, magnetic and theoretical studies show that the bimetallic pentalene complex, Mn-2(C8H41,4-SiiPr3)(2), contains both high and low spin Mn(II) in two very different sites.

引用

页码：873 / 875

页数：3

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