The first observation of the [Cp3Mn]- anion;: structures of hexagonal [(η2-Cp)3MnK•1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6]•2thf

被引：28

作者：

Bond, AD

Layfield, RA

MacAllister, JA

McPartlin, M

Rawson, JM

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 19期

关键词：

D O I：

10.1039/b106366a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexagonal [(eta (2)-Cp)(3)MnK .1.5thf] 1 and ion-separated [(eta (2)-Cp)(3)Mn](2)[Mg(thf)(6)]. 2thf 2 are obtained from reactions of CpK and Cp2Mg, respectively, with manganocene, Cp2Mn; they are the first complexes to be structurally characterised containing the [Cp3Mn](-) anion.

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页码：1956 / 1957

页数：2

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