The first observation of the [Cp3Mn]- anion;: structures of hexagonal [(η2-Cp)3MnK•1.5thf] and ion-separated [(η2-Cp)3Mn]2[Mg(thf)6]•2thf

被引：28

作者：

Bond, AD

Layfield, RA

MacAllister, JA

McPartlin, M

Rawson, JM

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Chem, London N7 8DB, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 19期

关键词：

D O I：

10.1039/b106366a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexagonal [(eta (2)-Cp)(3)MnK .1.5thf] 1 and ion-separated [(eta (2)-Cp)(3)Mn](2)[Mg(thf)(6)]. 2thf 2 are obtained from reactions of CpK and Cp2Mg, respectively, with manganocene, Cp2Mn; they are the first complexes to be structurally characterised containing the [Cp3Mn](-) anion.

引用

收藏

页码：1956 / 1957

页数：2

相关论文

共 32 条

[11]

COLLMAN JP, 1980, PRINCIPLES APPL ORGA, P13

[12] Solid state structures of cyclopentadienyllithium, -sodium, and -potassium. Determination by high-resolution powder diffraction [J].

Dinnebier, RE ;

Behrens, U ;

Olbrich, F .

ORGANOMETALLICS, 1997, 16 (17) :3855-3858

[13] ON THE METAL COORDINATION IN BASE-FREE TRIS(CYCLOPENTADIENYL) COMPLEXES OF THE LANTHANOIDS .2. THE X-RAY STRUCTURE OF (C5L5)3LAIII - A NOTABLY STABLE POLYMER DISPLAYING MORE THAN 3 DIFFERENT LA...C INTERACTIONS [J].

EGGERS, SH ;

KOPF, J ;

FISCHER, RD .

ORGANOMETALLICS, 1986, 5 (02) :383-385

[14] Synthesis and structure of [Cp2PbCpthf Na]•0.5thf;: implications to the control of dimensionality in p block metallocene anion systems (C = C5H5, Cpthf = {C5H4}CH2C4H7O) [J].

Feeder, N ;

Hopkins, AD ;

Layfield, RA ;

Wright, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (14) :2247-2248

[15] Recent developments in cyclopentadienyl-alkalimetal chemistry [J].

Harder, S .

COORDINATION CHEMISTRY REVIEWS, 1998, 176 :17-66

[16]

HECK J, 1988, ANGEW CHEM INT EDIT, V23, P7228

[17]

Heck J., 1984, ANGEW CHEM, V96, P699

[18] TERTIARY PHOSPHINE ADDUCTS OF MANGANESE(II) DICYCLOPENTADIENIDE - MAGNETIC STUDIES AND STRUCTURAL CHARACTERIZATION OF TILTED CYCLOPENTADIENYL RINGS [J].

HOWARD, CG ;

GIROLAMI, GS ;

WILKINSON, G ;

THORNTONPETT, M ;

HURSTHOUSE, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (07) :2033-2040

[19] REACTIVE ORGANOMETALLIC COMPOUNDS OBTAINED FROM METALLOCENES AND RELATED-COMPOUNDS AND THEIR SYNTHETIC APPLICATIONS [J].

JONAS, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (04) :295-311

[20] Metal alkyl and aryl compounds .55. Cyclopentadienyl and indenyl compounds off potassium and sodium [J].

Jordan, V ;

Behrens, U ;

Olbrich, F ;

Weiss, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 517 (1-2) :81-88

← 1 2 3 4 →