Synthesis and structure of [Cp2PbCpthf Na]•0.5thf;: implications to the control of dimensionality in p block metallocene anion systems (C = C5H5, Cpthf = {C5H4}CH2C4H7O)

被引：4

作者：

Feeder, N ^{[1
]}

Hopkins, AD ^{[1
]}

Layfield, RA ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b004608f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound [(Cp2PbCpNa)-Na-thf]. 0.5thf 1, obtained from the addition reaction of Cp2Pb with [(CpNa)-Na-thf . thf], provides the first opportunity to assess the structural impact of internal donation on aggregation within a p block metal cyclopentadienide anion system; the result being the adoption of an unusual polymeric sheet structure composed of [(Cp2PbCpNa)-Na-thf](3) rings.

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页码：2247 / 2248

页数：2

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