Electroless Ni-P coating preparation of conductive mica powder by a modified activation process

被引:45
作者
Dai, Hongbin [1 ]
Li, Hongxi [1 ]
Wang, Fuhui [1 ]
机构
[1] Chinese Acad Sci, Met Res Inst, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
关键词
electroless Ni-P coating; conductive powder; mica; activation;
D O I
10.1016/j.apsusc.2006.05.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
A modified activation process was developed for electroless Ni-P coating preparation of conductive mica powder. The electroless Ni-P coating process was modified by replacing the conventional sensitization and activation steps only using activation step with a Pd(II)-APTHS activator, which is a complex of Pd(II) ion with a derivate gamma-aminopropyttrihydroxysilane (APTHS) from the hydrolysis of gamma-aminopropyltriethoxysilane (APTES). The activated reaction progress and resulted Ni-P coating were characterized by XPS, SEM/EDX and TEM. Electroless nickel deposition was successfully initiated by this activation process. This activation process is very simple, and the obtained Ni-P deposits have the advantages of uniformity, continuity and densification. The average specific resistivity for the Ni-P coated mica powder was 4.85 x 10(-2) ohm cm. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:2474 / 2480
页数:7
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