High-temperature, high-pressure extraction of metallofullerenes Gd@C-2n

被引：7

作者：

Sun, DY ^{[1
]}

Liu, ZY ^{[1
]}

Guo, SH ^{[1
]}

Xu, WG ^{[1
]}

Liu, SY ^{[1
]}

机构：

[1] CHINESE ACAD SCI,CHANGCHUN INST APPL CHEM,KEY LAB APPL SPECT,CHANGCHUN 130022,JILIN,PEOPLES R CHINA

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1997年 / 5卷 / 01期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1080/15363839708011978

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A high-temperature, high-pressure extraction technique with toluene and pyridine were employed for the extraction of metallofullerenes Gd@C-2n, A series of Gd@C-2n for 2n from 70 to 96 were effectively extracted by toluene. Gd@C-74 was shown to be a new stable soluble metallofullerene species. Pyridine was found to be more useful for the extraction of Gd@C-82 and Gd-2@C-80 from empty fullerenes and other metallofullerene species.

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收藏

页码：137 / 147

页数：11

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