Entropy production in open volume-preserving systems

被引:73
作者
Gaspard, P
机构
[1] Ctr. Nonlinear Phenomena Complex S., Université Libre de Bruxelles, Campus Plaine, Code Postal 231
关键词
entropy production; flux boundary conditions; nonequilibrium steady state; singular measure; multibaker map; Takagi function;
D O I
10.1007/BF02732432
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We describe a mechanism leading to positive entropy production in volume-preserving systems under nonequilibrium conditions. We consider volume-preserving systems sustaining a diffusion process like the multibaker map or the Lorentz gas. A continuous flux of particles is imposed across the system resulting in a steady gradient of concentration. In the limit where such flux boundary conditions are imposed at arbitrarily separated boundaries for a fixed gradient, the invariant measure becomes singular. For instance, in the multibaker map, the limit invariant measure has a cumulative function given in terms of the nondifferentiable Takagi function. Because of this singularity of the invariant measure, the entropy must be defined as a coarse-grained entropy instead of the fined-grained Gibbs entropy, which would require the existence of a regular measure with a density. The coarse-grained entropy production is then shown to be asymptotically positive and, moreover, given by the entropy production expected from irreversible thermodynamics.
引用
收藏
页码:1215 / 1240
页数:26
相关论文
共 40 条
[1]   Entropy production for open dynamical systems [J].
Breymann, WG ;
Tel, T ;
Vollmer, J .
PHYSICAL REVIEW LETTERS, 1996, 77 (14) :2945-2948
[2]   STATISTICAL PROPERTIES OF LORENTZ GAS WITH PERIODIC CONFIGURATION OF SCATTERERS [J].
BUNIMOVICH, LA ;
SINAI, YG .
COMMUNICATIONS IN MATHEMATICAL PHYSICS, 1981, 78 (04) :479-497
[3]   MARKOV PARTITIONS FOR DISPERSED BILLIARDS [J].
BUNIMOVICH, LA ;
SINAI, YG .
COMMUNICATIONS IN MATHEMATICAL PHYSICS, 1980, 78 (02) :247-280
[4]   STEADY-STATE ELECTRICAL-CONDUCTION IN THE PERIODIC LORENTZ GAS [J].
CHERNOV, NI ;
EYINK, GL ;
LEBOWITZ, JL ;
SINAI, YG .
COMMUNICATIONS IN MATHEMATICAL PHYSICS, 1993, 154 (03) :569-601
[5]   DERIVATION OF OHM LAW IN A DETERMINISTIC MECHANICAL MODEL [J].
CHERNOV, NI ;
EYINK, GL ;
LEBOWITZ, JL ;
SINAI, YG .
PHYSICAL REVIEW LETTERS, 1993, 70 (15) :2209-2212
[6]   Stationary nonequilibrium states in boundary-driven Hamiltonian systems: Shear flow [J].
Chernov, NI ;
Lebowitz, JL .
JOURNAL OF STATISTICAL PHYSICS, 1997, 86 (5-6) :953-990
[7]  
Cornfeld I. P., 1982, Ergodic Theory
[8]  
de Groot S. R., 1984, Nonequilibrium thermodynamics
[9]   CHAOTIC SCATTERING-THEORY OF TRANSPORT AND REACTION-RATE COEFFICIENTS [J].
DORFMAN, JR ;
GASPARD, P .
PHYSICAL REVIEW E, 1995, 51 (01) :28-35
[10]  
Evans D.J., 1990, STAT MECH NONEQUILIB