Entropy production in open volume-preserving systems

被引:73
作者
Gaspard, P
机构
[1] Ctr. Nonlinear Phenomena Complex S., Université Libre de Bruxelles, Campus Plaine, Code Postal 231
关键词
entropy production; flux boundary conditions; nonequilibrium steady state; singular measure; multibaker map; Takagi function;
D O I
10.1007/BF02732432
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We describe a mechanism leading to positive entropy production in volume-preserving systems under nonequilibrium conditions. We consider volume-preserving systems sustaining a diffusion process like the multibaker map or the Lorentz gas. A continuous flux of particles is imposed across the system resulting in a steady gradient of concentration. In the limit where such flux boundary conditions are imposed at arbitrarily separated boundaries for a fixed gradient, the invariant measure becomes singular. For instance, in the multibaker map, the limit invariant measure has a cumulative function given in terms of the nondifferentiable Takagi function. Because of this singularity of the invariant measure, the entropy must be defined as a coarse-grained entropy instead of the fined-grained Gibbs entropy, which would require the existence of a regular measure with a density. The coarse-grained entropy production is then shown to be asymptotically positive and, moreover, given by the entropy production expected from irreversible thermodynamics.
引用
收藏
页码:1215 / 1240
页数:26
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