Chronocoulometric determination of doping levels of polythiophenes: influences of overoxidation and capacitive processes

被引：47

作者：

Tang, HQ

Zhu, LH

Harima, Y ^{[1
]}

Yamashita, K

机构：

[1] Hiroshima Univ, Venture Business Lab, Higashihiroshima 7398527, Japan

[2] Hiroshima Univ, Fac Integrated Arts & Sci, Higashihiroshima 7398521, Japan

来源：

SYNTHETIC METALS | 2000年 / 110卷 / 02期

基金：

日本学术振兴会;

关键词：

chronocoulometric determination; polythiophenes; overoxidation;

D O I：

10.1016/S0379-6779(99)00269-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Quasi-stationary determination of doping levels of polythiophenes has been successfully achieved in a wide potential window by using a modified potential-step chronocoulometric measurement of the charges consumed in oxidation and reduction processes of the polymers. Influences of experimental conditions, capacitive current-producing process and overoxidation process are discussed on the estimation of the doping levels of the polymers. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：105 / 113

页数：9

共 17 条

[11] IN-SITU IMPEDANCE MEASUREMENTS DURING OXIDATION AND REDUCTION OF CONDUCTING POLYMERS - SIGNIFICANCE OF THE CAPACITIVE CURRENTS [J].