Molecular complexes of phthalocyanine with organic solvents

被引：8

作者：

Lebedeva, NS ^{[1
]}

Trofimova, EV ^{[1
]}

Pavlycheva, NA ^{[1
]}

Vyugin, AI ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 38卷 / 08期

关键词：

Zinc; Benzene; Organic Chemistry; Pyridine; Comparative Analysis;

D O I：

10.1023/A:1020965913255

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It was established that in crystal solvates and solutions zinc(II)tetra-tert-butylphthalocyanine formed stable molecular complexes with benzene and pyridine. The characteristics of the corresponding molecular complexes were estimated. Molecules of electron-donor and aromatic solvents do not break down the zinc(II)tetra-tert-butylphthalocyanine associates and do not facilitate intraphase polymorphic transition. A comparative analysis was carried out for the coordinative properties of zinc(II)tetra-tert-butylphthalocyanine and its structural analog, zinc(II)tetrabenzoporphyrin, with respect to pyridine in benzene solutions.

引用

页码：1195 / 1199

页数：5

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