Surface structure of organoclays

被引：76

作者：

Heinz, H ^{[1
]}

Suter, UW ^{[1
]}

机构：

[1] ETH, Dept Mat, Inst Polymer, CH-8092 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 17期

关键词：

computer chemistry; conformation analysis; molecular dynamics; organic-inorganic interfaces; phase diagrams;

D O I：

10.1002/anie.200352747

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

While long and very short alkyl chains in alkylammonium-mica form a homogeneous mixture with remaining alkali ions on the mica surface, chains of medium length (≈C12) prefer island structures (see picture showing the type of system found for various degrees of surface coverage and chain length). This observation is described in detail and a thermodynamic explanation is given.

引用

页码：2239 / 2243

页数：5

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