Hydrogen-bond-assisted π-stacking of shape-persistent cyclophanes

被引：51

作者：

Lin, CH

Tour, J

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 22期

关键词：

D O I：

10.1021/jo025723a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The pi-stacking interaction between shape-persistent cyclophanes works cooperatively with multiple hydrogen bonding sites to form cyclophane dimers. These findings considerably broaden the applicability of pi-stacking interactions as a driving force in self-assembly chemistry. A gel formation effect was also noticed in one of the cyclophanes.

引用

页码：7761 / 7768

页数：8

共 37 条

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