Poly(alkylacetylenes): a new class of highly luminescent polyacetylenes

被引：25

作者：

Huang, YM

Lam, JWY

Cheuk, KKL

Ge, WK

Tang, BZ ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

[2] Hong Kong Univ Sci & Technol, Dept Phys, Kowloon, Hong Kong, Peoples R China

[3] Hong Kong Univ Sci & Technol, Ctr Display Res, Kowloon, Hong Kong, Peoples R China

来源：

THIN SOLID FILMS | 2000年 / 363卷 / 1-2期

关键词：

photoluminescence; monosubstituted polyacetylenes; poly(alkylacetylenes);

D O I：

10.1016/S0040-6090(99)01028-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

It is generally believed that monosubstituted polyacetylenes are unlikely candidates for photoluminescence (PL) materials, but we demonstrate here that poly(alkylacetylenes) are a class of highly luminescent monosubstituted polyacetylenes. Poly(alkylacetylenes) -{HC=C[(CH2)(m)R]}(n)- with R = OCO-Biph-OC7H15 [m = 2(2), 3(3), 4(4), 9(5)], CO2(CH2)(6)OCO-Biph-OC9H19 [m = 2(6), 8(7)], and OCO-Biph-OCOC11H23 [m = 4(8)] emit strong deep-blue light, readily observable by naked eyes under normal room illumination conditions. The PL intensity of (5) is at least six times higher than that of poly(1-phenyl-1-butyne), a well-known photoluminescent disubstituted polyacetylene. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：146 / 148

页数：3

共 24 条

[21] Synthesis and properties of stereoregular polyacetylenes containing cyano groups, poly[[4-[[[n-[(4'-cyano-4-biphenylyl)oxy]alkyl]oxy]carbonyl] phenyl]acetylenes] [J].