Kinetic control over the thermal stability of the In-H bond: Synthesis and characterization of amido indium hydride complexes

被引：32

作者：

Baker, RJ

Jones, C

Junk, PC

Kloth, M

机构：

[1] Univ Wales Coll Cardiff, Sch Chem, Cardiff CF10 3TB, S Glam, Wales

[2] Monash Univ, Sch Chem, Clayton, Vic 3168, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 29期

关键词：

amides; gallium; hydrides; indium; structure elucidation;

D O I：

10.1002/anie.200460304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High thermal stability is a characteristic feature of the depicted amido indium hydride complex (In red; hydride yellow), which is amongst the first to be synthesized and characterized. The stability arises from steric shielding of the In-H bond, which frustrates the formation of the intermolecular In-H-In bridges.

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收藏

页码：3852 / 3855

页数：4

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