A novel solid-liquid route for the preparation of Cu3Se2 and Ag2Se nanocrystals

被引：20

作者：

Yan, YL ^{[1
]}

Qian, XF ^{[1
]}

Xu, HJ ^{[1
]}

Yin, J ^{[1
]}

Zhu, ZK ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Natl Key Lab Composite Mat, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 01期

基金：

中国国家自然科学基金;

关键词：

photo-irradiation; solid-liquid synthetic route; nanocrystals; selenide;

D O I：

10.1016/S1387-7003(02)00673-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cu3Se2 and Ag2Se nanocrystals have been synthesized with Se as the precursor in aqueous solutions under photo-irradiation at room temperature. The obtained products were analyzed through X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The results showed that the tetragonal phase of Cu(3)Se(2)with nearly spherical grains and the orthorhombic phase of Ag2Se with nanoscale dendrite were formed. The experiments also confirmed that photo-irradiation and Na2SO3 played important roles in the formation of Cu3Se2 and Ag2Se nanocrystals. The formation mechanism of Cu3Se2 and Ag2Se nanocrystals was investigated in detail. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：34 / 37

页数：4

共 27 条

[1]

[Anonymous], MATER RES SOC SYMP P

[2]

CAMBI L, 1968, CHIM IND-MILAN, V50, P94

[3]

DOGHIOTTI L, 1968, J PHYS CHEM, V72, P1800

[4] Convenient, room-temperature liquid ammonia routes to metal chalcogenides [J].

Henshaw, G ;

Parkin, IP ;

Shaw, GA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (02) :231-236

[5] MnO2/polyimide hybrid materials prepared with a convenient ultraviolet irradiation technique [J].

Huang, JC ;

Zhu, ZK ;

Qian, XF ;

Yin, J .

MATERIALS RESEARCH BULLETIN, 2000, 35 (14-15) :2309-2315

[6] Photochemical deposition of Se and CdSe films from aqueous solutions [J].

Ichimura, M ;

Takeuchi, K ;

Nakamura, A ;

Arai, E .

THIN SOLID FILMS, 2001, 384 (02) :157-159

[7] Synthesis of silver selenide bicomponent nanoparticles by a novel technique: Laser-solid-liquid ablation [J].

Jiang, ZY ;

Huang, RB ;

Xie, SY ;

Xie, ZX ;

Zheng, LS .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 160 (02) :430-434

[8] Photoinduced conversion of silver nanospheres to nanoprisms [J].

Jin, RC ;

Cao, YW ;

Mirkin, CA ;

Kelly, KL ;

Schatz, GC ;

Zheng, JG .

SCIENCE, 2001, 294 (5548) :1901-1903

[9]

Korzhuev A. A., 1991, FIZ KHIM OBRAB MATER, V3, P131

[10] SELENIZATION OF CU AND IN THIN-FILMS FOR THE PREPARATION OF SELENIDE PHOTO-ABSORBER LAYERS IN SOLAR-CELLS USING SE VAPOR SOURCE [J].

LAKSHMIKUMAR, ST ;

RASTOGI, AC .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1994, 32 (01) :7-19

← 1 2 3 →