Challenges in engineering spin crossover:: Structures and magnetic properties of six alcohol solvates of iron(II) tris(2-picolylamine) dichloride

被引：167

作者：

Hostettler, M

Törnroos, KW

Chernyshov, D

Vangdal, B

Bürgi, HB

机构：

[1] Univ Bern, Lab Kristallog, CH-3012 Bern, Switzerland

[2] Univ Bergen, Dept Chem, N-5007 Bergen, Norway

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 35期

关键词：

crystal engineering; magnetic properties; solvate complexes; spin crossover; structure elucidation;

D O I：

10.1002/anie.200460736

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

So similar yet so different: The crystal structures of six alcohol solvates of the title compound (see formula) are found to be very similar at 200 K. In contrast, their spin-transition behavior and their structural phase transitions are quite different. Implications of these observations for crystal engineering are discussed.

引用

页码：4589 / 4594

页数：6

共 25 条

[1]

Boca R, 2003, SOLID STATE PHENOMEN, V90-91, P141

[2] Ordering phenomena and phase transitions in a spin-crossover compound-uncovering the nature of the intermediate phase of [Fe(2-PiC)3]Cl2•EtOH [J].