Poly(aryleneethynylene)s: Syntheses, properties, structures, and applications

被引:1707
作者
Bunz, UHF [1 ]
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
关键词
D O I
10.1021/cr990257j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conjugated polymers are organic semiconductors that are important materials for application in electronic and photonic devices. The class of conjugated polymers which has found the most attention in the past are undoubtedly the poly(p-phenylenevinylene)s which made big in the field of organic polymeric light emitting diodes. Only recently poly(phenylene-ethynylene)s (PPE) have demonstrated that their unique property profile are fantastic material in areas such as explosive detection, molecular wires in bridging nanogaps, and polarizers for liquid crystal displays. The synthesis, properties, structures, morphologies, and applications of types poly(aryleneethynylene)s are reviewed.
引用
收藏
页码:1605 / 1644
页数:40
相关论文
共 159 条
[51]   EXCIMERS AND EXCIPLEXES OF CONJUGATED POLYMERS [J].
JENEKHE, SA ;
OSAHENI, JA .
SCIENCE, 1994, 265 (5173) :765-768
[52]   Synthesis and reactions of metallo-diethynylbenzenes: building blocks for redox-active poly(phenyleneethynylene)s [J].
John, KD ;
Hopkins, MD .
CHEMICAL COMMUNICATIONS, 1999, (07) :589-590
[53]  
JONES D, 1998, UNPUB D JONES EPSCOR
[54]   NOVEL SYNTHESIS OF DISUBSTITUTED ALKYNE USING MOLYBDENUM CATALYZED CROSS-ALKYNE METATHESIS [J].
KANETA, N ;
HIKICHI, K ;
ASAKA, S ;
UEMURA, M ;
MORI, M .
CHEMISTRY LETTERS, 1995, (11) :1055-1056
[55]   Thiophene-based pi-conjugated emitting polymers: Synthesis and photophysical properties of poly[2-(dodecyloxy)-5-methyl-m-phenyleneethynylene] and poly[2-(dodecyloxy)-5-methyl-m-bis(ethynyl)phenyleneoligothienylene]s [J].
Kang, BS ;
Kim, DH ;
Lim, SM ;
Kim, J ;
Seo, ML ;
Bark, KM ;
Shin, SC ;
Nahm, K .
MACROMOLECULES, 1997, 30 (23) :7196-7201
[56]   Nanoscale fibrils and grids: Aggregated structures from rigid-rod conjugated polymers [J].
Kim, JS ;
McHugh, SK ;
Swager, TM .
MACROMOLECULES, 1999, 32 (05) :1500-1507
[57]   Poly(p-phenyleneethynylene)s are thermotropic liquid crystalline [J].
Kloppenburg, L ;
Jones, D ;
Claridge, JB ;
zur Loye, HC ;
Bunz, UHF .
MACROMOLECULES, 1999, 32 (13) :4460-4463
[58]   High molecular weight poly(p-phenyleneethynylene)s by alkyne metathesis utilizing "instant" catalysts:: A synthetic study [J].
Kloppenburg, L ;
Jones, D ;
Bunz, UHF .
MACROMOLECULES, 1999, 32 (13) :4194-4203
[59]   Alkyne metathesis with simple catalyst systems:: Poly(p-phenyleneethynylene)s [J].
Kloppenburg, L ;
Song, D ;
Bunz, UHF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (31) :7973-7974
[60]   SYNTHESIS AND NONLINEAR OPTICS OF SOLUBLE POLY(PHENYLENEETHYNYLENE) [J].
KONDO, K ;
OKUDA, M ;
FUJITANI, T .
MACROMOLECULES, 1993, 26 (26) :7382-7382