Catalysed low temperature H2 release from nitrogen heterocycles

被引：125

作者：

Moores, Audrey

Poyatos, Macarena

Luo, Yi ^{[1
]}

Crabtree, Robert H.

机构：

[1] Albanova Univ Ctr, Royal Inst Technol, Dept Theoret Chem, S-1069 Stockholm, Sweden

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 11期

关键词：

D O I：

10.1039/b608914c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In an experimental and computational study, nitrogen- and oxygen-containing heterocycles were compared with carbocycles as liquid substrates for hydrogen release with heterogeneous catalysts. Heteroatom substitution, particularly by nitrogen, favours low temperature H-2 release; indoline was fully dehydrogenated in less than 30 min with Pd/C at 110 degrees C.

引用

收藏

页码：1675 / 1678

页数：4

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