Trapping Formaldehyde in the Homogeneous Catalytic Reduction of Carbon Dioxide

被引：86

作者：

Bontemps, Sebastien ^{[1
,2
]}

Sabo-Etienne, Sylviane ^{[1
,2
]}

机构：

[1] CNRS, LCC, F-31077 Toulouse, France

[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 39期

关键词：

acetals; borane; CO2; reduction; formaldehyde; ruthenium; N-HETEROCYCLIC CARBENE; NMR-SPECTROSCOPY; CO2; INSERTION; FORMIC-ACID; HYDROGENATION; METHANOL; CONVERSION; TRANSFORMATION; COMPLEX; TECHNOLOGIES;

D O I：

10.1002/anie.201304025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formaldehyde detectives: Evidence for the production of formaldehyde during a ruthenium-catalyzed CO2 reduction process, and for its involvement in the formation of the resulting C2 compound, is disclosed. Ultimately, formaldehyde can be recovered by methanol trapping. HBPin=pinacolborane. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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收藏

页码：10253 / 10255

页数：3

相关论文

共 66 条

[1]

[Anonymous], 1995, Angew. Chem., DOI DOI 10.1002/ANGE.19951072005

[2] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].

Arakawa, H ;

Aresta, M ;

Armor, JN ;

Barteau, MA ;

Beckman, EJ ;

Bell, AT ;

Bercaw, JE ;

Creutz, C ;

Dinjus, E ;

Dixon, DA ;

Domen, K ;

DuBois, DL ;

Eckert, J ;

Fujita, E ;

Gibson, DH ;

Goddard, WA ;

Goodman, DW ;

Keller, J ;

Kubas, GJ ;

Kung, HH ;

Lyons, JE ;

Manzer, LE ;

Marks, TJ ;

Morokuma, K ;

Nicholas, KM ;

Periana, R ;

Que, L ;

Rostrup-Nielson, J ;

Sachtler, WMH ;

Schmidt, LD ;

Sen, A ;

Somorjai, GA ;

Stair, PC ;

Stults, BR ;

Tumas, W .

CHEMICAL REVIEWS, 2001, 101 (04) :953-996

[3] Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].

Aresta, Michele ;

Dibenedetto, Angela .

DALTON TRANSACTIONS, 2007, (28) :2975-2992

[4]

Ashley A. E., 2009, Angew.Chem., V121, P10023, DOI [10.1002/ange.200905466, DOI 10.1002/ANGE.200905466]

[5] Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH [J].

Ashley, Andrew E. ;

Thompson, Amber L. ;

O'Hare, Dermot .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9839-9843

[6] Decamethylscandocinium-hydrido-(perfluorophenyl)-borate: fixation and tandem tris(perfluorophenyl)-borane catalysed deoxygenative hydrosilation of carbon dioxide [J].

Berkefeld, Andreas ;

Piers, Warren E. ;

Parvez, Masood ;

Castro, Ludovic ;

Maron, Laurent ;

Eisenstein, Odile .

CHEMICAL SCIENCE, 2013, 4 (05) :2152-2162

[7] Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide [J].

Berkefeld, Andreas ;

Piers, Warren E. ;

Parvez, Masood .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (31) :10660-10661

[8]

Bontemps S., 2012, Angew. Chem. Int. Ed, V124, P1703, DOI DOI 10.1002/ANGE.201107352

[9] Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds [J].

Bontemps, Sebastien ;

Vendier, Laure ;

Sabo-Etienne, Sylviane .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (07) :1671-1674

[10] THE PATH OF CARBON IN PHOTOSYNTHESIS [J].

CALVIN, M ;

BENSON, AA .

SCIENCE, 1948, 107 (2784) :476-480

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