Design of extended surface-supported chiral metal-organic arrays comprising mononuclear iron centers

被引：48

作者：

Dmitriev, A ^{[1
]}

Spillmann, H

Lingenfelder, M

Lin, N

Barth, JV

Kern, K

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

[2] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland

[3] Univ British Columbia, Adv Mat & Proc Engn Lab, Vancouver, BC V6T 1Z4, Canada

来源：

LANGMUIR | 2004年 / 20卷 / 12期

关键词：

D O I：

10.1021/la049273o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A design strategy for fabricating a surface-supported chiral metal-organic system comprising a regular arrangement of mononuclear iron centers and nanocavities is presented. By sequential deposition of 1,2,4-benzenetricarboxylic acid (tmla) molecules and iron atoms on a Cu(100) surface under ultrahigh vacuum conditions, chiral square-planar Fe(tmla)(4) metal-organic complexes are generated, which order in extended homochiral arrays. Structure formation and envisioned functionality of such metal-organic architectures are discussed.

引用

页码：4799 / 4801

页数：3

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