Closed and Open Clamlike Structures Formed by Hydrogen-Bonded Pairs of Cyclotricatechylene Anions that Contain Cationic "Meat"

被引：42

作者：

Abrahams, Brendan F. ^{[1
]}

FitzGerald, Nicholas J. ^{[1
]}

Hudson, Timothy A. ^{[1
]}

Robson, Richard ^{[1
]}

Waters, Tom ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 17期

基金：

澳大利亚研究理事会;

关键词：

catechols; cation trapping; hydrogen bonding; inclusion compounds; supramolecular chemistry; CRYSTAL-STRUCTURES; CYCLOTRIVERATRYLENE; MOLECULES;

D O I：

10.1002/anie.200805789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Clamming up: The hexaphenolic compound cyclotricatechylene, which has a bowl-shaped cavity, forms clamlike pairs that encapsulate cations (see picture). Variable hydrogen bonding allows two linked cyclotricatechylene clamshells to be in a closed arrangement when smaller cations such Rb+ or Cs +provide the clam meat, whereas larger cations such as NMe 4+ and NEt4+ cause the clam to be partially opened. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3129 / 3132

页数：4