Polyelectrolyte brushes as efficient ultrathin platforms for site-selective copper electroless deposition

被引：79

作者：

Azzaroni, Omar

Zheng, Zijian

Yang, Zhongqiang

Huck, Wilhelm T. S.

机构：

[1] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England

[2] Univ Cambridge, Nanosci Ctr, Cambridge CB3 0FF, England

来源：

LANGMUIR | 2006年 / 22卷 / 16期

关键词：

D O I：

10.1021/la060891+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ion-exchange in surface-initiated polyelectrolyte brushes provides a versatile route to the formation of catalytically active surfaces for electroless deposition of Cu. The advantage of this procedure is the covalent anchoring of the catalyst support layer, eliminating delamination of the metal film, even when deposited onto PDMS substrates. Furthermore, by tuning the concentration of PdCl42- ions in the brushes, the rate of deposition and hence the thickness of the overall film can be controlled easily.

引用

收藏

页码：6730 / 6733

页数：4

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