Thermal and electrochemical studies of carbons for Li-ion batteries 2. Correlation of active sites and irreversible capacity loss

被引:26
作者
Tran, T
Yebka, B
Song, X
Nazri, G
Kinoshita, K [1 ]
Curtis, D
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA
[2] Lawrence Livermore Natl Lab, Dept Chem & Mat Sci, Livermore, CA 94550 USA
[3] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
关键词
irreversible capacity; carbon structure; Li-ion batteries;
D O I
10.1016/S0378-7753(99)00343-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) involving air oxidation of fluid coke, coal-tar pitch delayed coke and needle coke suggested that active sites are I,resent which can be correlated to the crystallographic parameters, L-a and L-c, and the d(002) spacing. This finding was extended to determine the relationship between active sites on carbon and their role in catalyzing electrolyte decomposition leading to irreversible capacity loss (ICL) in Li-ion batteries. Electrochemical data from this study with graphitizable carbons and from published Literature were analyzed to determine the relationship between the physical properties of carbon and the ICL during the first charge/discharge cycle. Based on this analysis, we conclude that the active surface area, and not the total BET surface area, has an influence on the ICL of carbo,ns for Li-ion batteries. This conclusion suggests that the carbon surface structure plays a significant role in catalyzing electrolyte decomposition. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:269 / 278
页数:10
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