Fabrication of highly photoluminescent TiO2/PPV hybrid nanoparticle-polymer fibers by electrospinning

被引:49
作者
Wang, Cheng [1 ]
Yan, Eryun
Huang, Zonghao
Zhao, Qiang
Xin, Yi
机构
[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
[2] Heilongjiang Univ, Sch Chem & Mat Sci, Polymer Chem Lab, Harbin 150080, Peoples R China
关键词
electrospinning; fibers; nanoparticles; photoluminescent; poly(phenylene vinylene);
D O I
10.1002/marc.200600626
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, we have synthesized highly photolumine scent TiO2/poly (phenylene vinylene) (PPV) hybrid nanoparticle-polymer fibers by electrospinning a PPV precursor added to a TiO2 sol-gel solution. The diameters of the hybrid fibers ranged from 100-300 nm and the average size of TiO2 nanoparticles within the fibers was 10-60 nm. FT-IR analysis indicated that a new band around 1632 cm(-1) assigned to the Ti-O-C vibration appeared, which resulted in the stronger luminance of the fluorescence of the TiO2/PPV hybrid fibers compared to free standing PPV nanofibers.
引用
收藏
页码:205 / 209
页数:5
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