Synthesis and properties of a novel redox driven chemiluminescent material built on a terthienyl system

被引：20

作者：

Atilgan, Nurdan ^{[1
]}

Algi, Fatih ^{[2
]}

Onal, Ahmet M. ^{[1
]}

Cihaner, Atilla ^{[3
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

[2] Canakkale Onsekiz Mart Univ, LOM, TR-17100 Canakkale, Turkey

[3] Atilim Univ, Fac Engn, Chem Grp, TR-06836 Ankara, Turkey

来源：

TETRAHEDRON | 2009年 / 65卷 / 29-30期

关键词：

Chemiluminescence; Sensors; Luminol; Forensic science; Conducting polymers; FILM-MODIFIED ELECTRODES; ELECTROCATALYTIC PROPERTIES; CAPILLARY-ELECTROPHORESIS; HYDROGEN-PEROXIDE; LUMINOL; ACID; ELECTROCHEMILUMINESCENCE; GLUCOSE; BLOOD;

D O I：

10.1016/j.tet.2009.05.019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel redox driven chemiluminescent material built on a terthienyl system, namely 5,7-di-ethylenedioxythiophen-2-yl-2,3-dihydro-thieno[3,4-d]pyridazine-1,4-dione (ETE-Lum), which is soluble in both organic media and basic aqueous solution was synthesized and characterized. Furthermore, its polymer, PETE-Lum, which is one of the most rare examples of chemiluminescent polymeric materials bearing a pyridazine unit, was obtained successfully by electrochemical means. Both of the materials give chemiluminescence either by treatment with oxidants (H2O2 and/or KMnO4) or by the application of a potential pulse. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：5776 / 5781

页数：6

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