Synthesis and its stereochemistry of aminophosphonic acids derived from 5-hydroxymethylfurfural

被引：25

作者：

Cottier, L

Descotes, G

Lewkowski, J

Skowronski, R

机构：

[1] UNIV LODZ,DEPT ORGAN CHEM,PL-90136 LODZ,POLAND

[2] UNIV LYON 1,URA CNRS 463,CHIM ORGAN LAB,F-69622 VILLEURBANNE,FRANCE

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1996年 / 116卷

关键词：

5-hydroxymethylfurfural; imine; stereoselective addition; aminofurfurylphosphonates;

D O I：

10.1080/10426509608040472

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some dialkyl N-substituted-alpha-amino-alpha-furylmethanephosphonates were synthesized via the addition of dialkyl phosphites to corresponding imines in mild conditions in a short time. When an imine is chirally N-substituted the reaction is stereoselective. Stereochemical aspects of the reaction in the light of Cram rules is discussed in this paper.

引用

页码：93 / 100

页数：8

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