Double-layer capacitance of waste coffee ground activated carbons in an organic electrolyte

被引:150
作者
Rufford, Thomas E. [1 ]
Hulicova-Jurcakova, Denisa [1 ]
Fiset, Erika [1 ]
Zhu, Zhonghua [1 ]
Lu, Gao Qing [1 ]
机构
[1] Univ Queensland, ARC Ctr Excellence Funct Nanomat, Sch Engn, Brisbane, Qld 4072, Australia
基金
澳大利亚研究理事会;
关键词
Double-layer capacitor; Activated carbon; Food waste; Energy storage; Electrochemical impedance; CHEMICAL ACTIVATION; ELECTROCHEMICAL CAPACITORS; PORE-SIZE; SUPERCAPACITORS;
D O I
10.1016/j.elecom.2009.02.038
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Using ZnCl(2) activation we prepared a series of carbon electrodes from waste coffee grounds to study the effect of mesopores on double-layer capacitance in a tetraethyl ammonium tetrafluoroborate/acetonitrile electrolyte. The activated carbon with the largest mesopore volume achieved an energy density of 34 Wh kg(-1) at low current loads, and significantly retained an energy density of 16.5 Wh kg(-1) and specific capacitance of more than 100 F g(-1) at fast charge-discharge rates (20 A g(-1)). The effect of mesopores on capacitance at fast charge-discharge rates is discussed. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:974 / 977
页数:4
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