Multi-nucleation-based formation of oriented zinc oxide microcrystals and films in aqueous solutions

被引:25
作者
Hirano, S [1 ]
Masuya, K [1 ]
Kuwabara, M [1 ]
机构
[1] Univ Tokyo, Grad Sch Engn, Dept Mat Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1021/jp038014p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A wet-chemical deposition method of synthesizing highly oriented, transparent ZnO films on a crystalline template is described. Multi-nucleation and the subsequent growth of ZnO nanodomains at an early stage of wet-chemical deposition leads to the formation of thin hexagonal platelike ZnO crystals spread over the template film. A subsequent temperature increase allows the growth of oriented rods, whose size depends on that of the platelike crystals. Consequently, oriented ZnO films with various microstructures can be synthesized by controlling the size of the ZnO plates at an early stage of deposition.
引用
收藏
页码:4576 / 4578
页数:3
相关论文
共 15 条
[1]   Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products [J].
Banfield, JF ;
Welch, SA ;
Zhang, HZ ;
Ebert, TT ;
Penn, RL .
SCIENCE, 2000, 289 (5480) :751-754
[2]  
Boyle DS, 2002, CHEM COMMUN, P80, DOI 10.1039/b110079n
[3]   Room-temperature ultraviolet nanowire nanolasers [J].
Huang, MH ;
Mao, S ;
Feick, H ;
Yan, HQ ;
Wu, YY ;
Kind, H ;
Weber, E ;
Russo, R ;
Yang, PD .
SCIENCE, 2001, 292 (5523) :1897-1899
[4]   Hydrothermal synthesis of ZnO nanorods in the diameter regime of 50 nm [J].
Liu, B ;
Zeng, HC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (15) :4430-4431
[5]   TOPOTACTICAL REACTIONS WITH FERRIMAGNETIC OXIDES HAVING HEXAGONAL CRYSTAL STRUCTURES .1. [J].
LOTGERING, FK .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1959, 9 (02) :113-+
[6]   Sol-gel preparation of ZnO films with extremely preferred orientation along (002) plane from zinc acetate solution [J].
Ohyama, M ;
Kozuka, H ;
Yoko, T .
THIN SOLID FILMS, 1997, 306 (01) :78-85
[7]  
Pacholski C, 2002, ANGEW CHEM INT EDIT, V41, P1188, DOI 10.1002/1521-3773(20020402)41:7<1188::AID-ANIE1188>3.0.CO
[8]  
2-5
[9]   Imperfect oriented attachment: Dislocation generation in defect-free nanocrystals [J].
Penn, RL ;
Banfield, JF .
SCIENCE, 1998, 281 (5379) :969-971
[10]   Epitaxial assembly in aged colloids [J].
Penn, RL ;
Oskam, G ;
Strathmann, TJ ;
Searson, PC ;
Stone, AT ;
Veblen, DR .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (11) :2177-2182