Structure-antioxidant relationship of flavonoids from fermented rooibos

被引:51
作者
Krafczyk, Nicole [1 ]
Woyand, Franziska [1 ]
Glomb, Marcus A. [1 ]
机构
[1] Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Germany
关键词
Fremy's salt; LDL-oxidation; Rooibos tea; Structure-antioxidant relationship; TEAC; TEA ASPALATHUS-LINEARIS; ABTS RADICAL-CATION; PHENOLIC-COMPOUNDS; TOCOPHEROL;
D O I
10.1002/mnfr.200800117
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Rooibos tea (Aspalathus linearis) contains different bioactive phenolic Compounds such as dihydrochalcones, flavonols, flavanones, flavones, and flavanols. Flavonoids isolated from rooibos were subjected to different in vitro assays: Trolox equivalent antioxidant activity, LDL oxidation and Fremy's salt assays to determine the total antioxidant activity (TAA), Assay results were compared, and the structure-antioxidant relationship was investigated. A decoupled LDL oxidation test was established with the objective of having an assay adapted more to an in vivo situation. The different in vitro methods were coupled offline to HPLC-DAD. Results from these Coupled offline methods were compared to the TAA to assess the usefulness of the coupling setup.
引用
收藏
页码:635 / 642
页数:8
相关论文
共 18 条
[11]   ROOIBOS TEA, ASPALATHUS-LINEARIS, A CAFFEINELESS, LOW-TANNIN BEVERAGE [J].
MORTON, JF .
ECONOMIC BOTANY, 1983, 37 (02) :164-173
[12]   Antioxidant activity applying an improved ABTS radical cation decolorization assay [J].
Re, R ;
Pellegrini, N ;
Proteggente, A ;
Pannala, A ;
Yang, M ;
Rice-Evans, C .
FREE RADICAL BIOLOGY AND MEDICINE, 1999, 26 (9-10) :1231-1237
[13]   Structure-antioxidant activity relationships of flavonoids and phenolic acids [J].
RiceEvans, CA ;
Miller, NJ ;
Paganga, G .
FREE RADICAL BIOLOGY AND MEDICINE, 1996, 20 (07) :933-956
[14]   Structure-antioxidant efficiency relationships of phenolic compounds and their contribution to the antioxidant activity of sea buckthorn juice [J].
Rösch, D ;
Bergmann, M ;
Knorr, D ;
Kroh, LW .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (15) :4233-4239
[15]   PROTECTIVE EFFECT OF EPICATECHIN, EPICATECHIN GALLATE, AND QUERCETIN ON LIPID-PEROXIDATION IN PHOSPHOLIPID-BILAYERS [J].
TERAO, J ;
PISKULA, M ;
YAO, Q .
ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1994, 308 (01) :278-284
[16]   VARIABILITY IN LIPOPROTEIN CONCENTRATIONS IN SERUM AFTER PROLONGED STORAGE AT -20-DEGREES-C [J].
TIEDINK, HGM ;
KATAN, MB .
CLINICA CHIMICA ACTA, 1989, 180 (02) :147-155
[17]  
vonGadow A, 1997, FOOD CHEM, V60, P73, DOI 10.1016/S0308-8146(96)00312-3
[18]   Interactive effects of polyphenols, tocopherol and ascorbic acid on the Cu2+-mediated oxidative modification of human low density lipoproteins [J].
Yeomans, VC ;
Linseisen, J ;
Wolfram, G .
EUROPEAN JOURNAL OF NUTRITION, 2005, 44 (07) :422-428