New transparent chalcogenide materials using a sol-gel process

被引：71

作者：

Gacoin, T ^{[1
]}

Malier, L ^{[1
]}

Boilot, JP ^{[1
]}

机构：

[1] ECOLE POLYTECH,PHYS MAT CONDENSEE LAB,CNRS,URA 1254D,F-91128 PALAISEAU,FRANCE

来源：

CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 07期

关键词：

D O I：

10.1021/cm970103p

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report a scheme for the IE-VI chalcogenide sol-gel synthesis, using cadmium sulfide as a model system. Highly concentrated sols are obtained by surface complexation of CdS nanocrystals with 4-fluopophenylthiol. Controlled aggregation and gelation is then achieved by a progressive decomplexation of the particles via a thiol oxidation reaction. The gels may finally be processed as solid monoliths or thin films and dried to obtain transparent nanostructured materials.

引用

页码：1502 / &

页数：4

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