Testing carbon-coated VOx prepared via reaction under autogenic pressure at elevated temperature as Li-insertion materials

被引:142
作者
Odani, Ayelet
Pol, Vilas Ganpat
Pol, Swati Vilas
Koltypin, Maxim
Gedanken, Aharon [1 ]
Aurbach, Doron
机构
[1] Bar Ilan Univ, Ctr Adv Mat & Nanotechnol, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Bar Ilan Univ, Ctr Adv Mat & Nanotechnol, Kanbar Lab Nanomat, IL-52900 Ramat Gan, Israel
[3] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
关键词
D O I
10.1002/adma.200501611
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
V2O3 nanoparticles covered by a 15 nm thick uniform carbon coating are prepared by reaction under autogenic pressure at elevated temperature of VO(OC2H5)(3) at 700 degrees C. Further oxidation of this material produces carbon-coated V2O5 nanoparticles. Both materials reversibly insert Li (see figure) electrochemically in nonaqueous Li-salt solutions.
引用
收藏
页码:1431 / +
页数:7
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