15 and 30-membered polyolefinic macrocycles.: Periphery modification by aromatic nucleophilic substitution of fluorine

被引:15
作者
Moreno-Mañas, M [1 ]
Spengler, J [1 ]
机构
[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain
关键词
macrocycles; aromatic nucleophilic substitution; alkene; phosphane; palladium complex; nitrogen heterocycle; cyclization;
D O I
10.1016/S0040-4020(02)00934-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tris[(4-fluorophenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene is a pivotal 15-membered triolefinic macrocycle from which a vast array of different derivatives are prepared by substitution of fluorine atoms. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:7769 / 7774
页数:6
相关论文
共 25 条
[1]  
Baxter I, 2000, CHEM-EUR J, V6, P4285, DOI 10.1002/1521-3765(20001201)6:23<4285::AID-CHEM4285>3.3.CO
[2]  
2-4
[3]   Water-soluble phosphines .6. Tailor-made syntheses of chiral secondary and tertiary phosphines with sulfonated aromatic substituents: Structural and quantum chemical studies [J].
Bitterer, F ;
Herd, O ;
Hessler, A ;
Kuhnel, M ;
Rettig, K ;
Stelzer, O ;
Sheldrick, WS ;
Nagel, S ;
Rosch, N .
INORGANIC CHEMISTRY, 1996, 35 (14) :4103-4113
[4]   Preparation of nitrogen-containing 20-membered tetraolefinic macrocycles:: (E,E,E,E)-1,6,11,16-tetra(arylsulfonyl)-1,6,11,16-tetraaza-cycloicosa-3,8,13,18-tetraenes [J].
Blanco, B ;
Cerezo, S ;
Moreno-Mañas, M ;
Pleixats, R ;
Spengler, J .
TETRAHEDRON LETTERS, 2001, 42 (51) :9001-9003
[5]  
Cerezo S, 2001, EUR J INORG CHEM, P1999
[6]  
Cerezo S, 2001, EUR J ORG CHEM, V2001, P329
[7]   Metal complexes of 15-membered triolefinic macrocycles, (E,E,Z)-1,6,11-tris[(2,4,6-triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene and its palladium(0), platinum(0), and silver(I) complexes [J].
Cortès, J ;
Moreno-Mañas, M ;
Pleixats, R .
TETRAHEDRON LETTERS, 2001, 42 (26) :4337-4339
[8]  
Cortés J, 2000, EUR J ORG CHEM, V2000, P239
[9]  
DIETRICH B, 1991, ASPECTS CHIMIE COMPO
[10]   TEMPLATE SYNTHESIS OF A BIMETALLIC COMPLEX OF A 30-MEMBERED DECADENTATE MACROCYCLIC LIGAND - CRYSTAL AND MOLECULAR-STRUCTURE OF A LEAD(II) COMPLEX [J].
DREW, MGB ;
RODGERS, A ;
MCCANN, M ;
NELSON, SM .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (09) :415-416