Tantalum(V) complexes of an amine triphenolate ligand: a dramatic difference in reactivity between the two labile positions

被引：28

作者：

Groysman, S

Segal, S

Shamis, M

Goldberg, I

Kol, M ^{[1
]}

Goldschmidt, Z

Hayut-Salant, E

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

[3] Coll Judea & Samaria, IL-44387 Ariel, Israel

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 18期

关键词：

D O I：

10.1039/b206759e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tetradentate trianionic amine triphenolate ligand leads to octahedral Ta(v) complexes of C-s-symmetry, in which the two labile positions that are in cis geometry exhibit a dramatic difference in reactivity, the position trans to a phenoxy group being the active one.

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收藏

页码：3425 / 3426

页数：2

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