Syntheses and structures of the open-framework phases (CH3NH3)3•Zn4O(AsO4)3 and (CH3NH3)3•Zn4O(PO4)3 related to the M3Zn4O(XO4)3•nH2O family

被引：42

作者：

Harrison, WTA ^{[1
]}

Phillips, MLF

Chavez, AV

Nenoff, TM

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

[2] Gemfire Corp, Palo Alto, CA 94303 USA

[3] Sandia Natl Labs, Catalysis & Chem Technol Dept, Albuquerque, NM 87185 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 12期

关键词：

D O I：

10.1039/a906009j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)(3). Zn4O(AsO4)(3) and (CH3NH3)(3). Zn4O(PO4)(3) are reported. These compounds are built up from vertex-sharing three-dimensional "OZn4" + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)(3). nH(2)O family of phases.

引用

页码：3087 / 3092

页数：6

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