Synthesis, reactivity, and ligand properties of a stable alkyl carbene

被引：155

作者：

Lavallo, V

Mafhouz, J

Canac, Y

Donnadieu, B

Schoeller, WW

Bertrand, G ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, UCR, CNRS,UMR 2282,Joint Res Chem Lab, Riverside, CA 92521 USA

[2] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 28期

关键词：

D O I：

10.1021/ja047503f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments. Copyright © 2004 American Chemical Society.

引用

页码：8670 / 8671

页数：2

共 44 条

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