Mechanism of thermal isomerization of azobenzene in zeolite cavities

被引：16

作者：

Kuriyama, Y ^{[1
]}

Oishi, S ^{[1
]}

机构：

[1] Kitasato Univ, Sch Sci, Dept Chem, Sagamihara, Kanagawa 2288555, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 10期

关键词：

D O I：

10.1246/cl.1999.1045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The life time of cis-azobenzene in zeolite supercage is twenty times longer than that in benzene at room temperature. The kinetic studies indicate that the thermal isomerization proceeds through inversion mechanism. Activation parameters show that the zeolite nanospace gives the same environment as that of gas phase.

引用

页码：1045 / 1046

页数：2

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