The assembly of pentanuclear nickel(II) complexes from asymmetric compartmental ligands and bearing μ3-OH bridges

被引：25

作者：

Adams, H ^{[1
]}

Clunas, S ^{[1
]}

Fenton, DE ^{[1
]}

Towers, DN ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 21期

关键词：

D O I：

10.1039/b207631b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric di-aminic compartmental ligands HL5-HL7 form pentanuclear nickel(II) complexes in which the core is assembled from two dinuclear [Ni2L] units which are each linked to the third Ni atom by bridging mu(3)-hydroxo groups; the crystal structure of [Ni-5(L-5)(2)(OAc)(6)(OH)(2)], 1 [HL5 is the proligand 2-{[(2-dimethylaminoethyl)ethylamino]methyl}-6-ethyliminomethyl-4-methylphenol] is reported.

引用

页码：3933 / 3935

页数：3

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