Structure of water adsorbed on a mica surface

被引：172

作者：

Park, SH ^{[1
]}

Sposito, G ^{[1
]}

机构：

[1] Lawrence Berkeley Natl Lab, Div Earth Sci, Dept Geochem, Berkeley, CA 94720 USA

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 89卷 / 08期

关键词：

D O I：

10.1103/PhysRevLett.89.085501

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Monte Carlo simulations of hydration water on the mica (001) surface under ambient conditions revealed water molecules bound closely to the ditrigonal cavities in the surface, with a lateral distribution of approximately one per cavity, and water molecules (interposed between K+ counter ions) in a layer situated about 2.5 Angstrom from a surface O along a direction normal to the (001) plane. The calculated water O density profile was in quantitative agreement with recent x-ray reflectivity measurements indicating strong lateral ordering of the hydration water but liquidlike disorder otherwise.

引用

页数：3

共 18 条

[1] Dynamics of supercooled water in confined geometry [J].

Bergman, R ;

Swenson, J .

NATURE, 2000, 403 (6767) :283-286

[2]

Brindley G.W., 1980, CRYSTAL STRUCTURE CL, P125, DOI DOI 10.1180/MONO-5

[3]

CHANG FRC, 1999, ACS SYM SER, V715, P88

[4] Molecular-scale density oscillations in water adjacent to a mica surface [J].

Cheng, L ;

Fenter, P ;

Nagy, KL ;

Schlegel, ML ;

Sturchio, NC .

PHYSICAL REVIEW LETTERS, 2001, 87 (15) :156103-156103

[5] Monte Carlo and molecular dynamics studies of interlayer structure in Li(H2O)3-smectites [J].

Greathouse, J ;

Sposito, G .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (13) :2406-2414

[6] Molecular dynamics simulation of water mobility in magnesium-smectite hydrates [J].

Greathouse, JA ;

Refson, K ;

Sposito, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (46) :11459-11464

[7] Solvent structure, dynamics, and ion mobility in aqueous solutions at 25°C [J].

Koneshan, S ;

Rasaiah, JC ;

Lynden-Bell, RM ;

Lee, SH .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (21) :4193-4204

[8] From hydrophobic to hydrophilic behaviour: A simulation study of solvation entropy and free energy of simple solutes [J].

LyndenBell, RM ;

Rasaiah, JC .

JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (06) :1981-1991

[9] CL STUDY OF WATER DIMER POTENTIAL SURFACE [J].

MATSUOKA, O ;

CLEMENTI, E ;

YOSHIMINE, M .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (04) :1351-1361

[10] Icelike water monolayer adsorbed on mica at room temperature [J].

Miranda, PB ;

Xu, L ;

Shen, YR ;

Salmeron, M .

PHYSICAL REVIEW LETTERS, 1998, 81 (26) :5876-5879

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