Ruthenium-catalyzed regioselective α-alkylation of ketones with primary alcohols

被引：161

作者：

Cho, CS ^{[1
]}

Kim, BT

Kim, TJ

Shim, SC

机构：

[1] Kyungpook Natl Univ, Ind Technol Res Inst, Taegu 702701, South Korea

[2] Kyungpook Natl Univ, Dept Ind Chem, Taegu 702701, South Korea

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 44期

关键词：

alkylation; ketones; primary alcohols; ruthenium catalyst;

D O I：

10.1016/S0040-4039(02)01625-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketones are regio selectively alkylated with an array of primary alcohols in dioxane at 80degreesC in the presence of a catalytic amount of a ruthenium catalyst together with KOH and a hydrogen acceptor. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：7987 / 7989

页数：3

共 25 条

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