Simple Method of Preparing Graphene Flakes by an Arc-Discharge Method

被引:467
作者
Subrahmanyam, K. S. [1 ,2 ]
Panchakarla, L. S. [1 ,2 ]
Govindaraj, A. [1 ,2 ,3 ]
Rao, C. N. R. [1 ,2 ,3 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
[2] Jawaharlal Nehru Ctr Adv Sci Res, CSIR Ctr Excellence Chem, Bangalore 560064, Karnataka, India
[3] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
关键词
CARBON NANOTUBES; GRAPHITE; HYDROGEN; SHEETS; PHASE; FILMS; SUBSTRATE; GAS;
D O I
10.1021/jp900791y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Arc discharge between graphite electrodes under a relatively high pressure of hydrogen yields graphene flakes generally containing 2-4 layers in the inner wall region of the arc chamber. The graphene flakes so obtained have been characterized by X-ray diffraction, atomic force microscopy, transmission electron microscopy, and Raman spectroscopy. The method is eminently suited to dope graphene with boron and nitrogen by carrying out arc discharge in the presence of diborane and pyridine respectively.
引用
收藏
页码:4257 / 4259
页数:3
相关论文
共 27 条
[1]   Structure and electronic properties of graphite nanoparticles [J].
Andersson, OE ;
Prasad, BLV ;
Sato, H ;
Enoki, T ;
Hishiyama, Y ;
Kaburagi, Y ;
Yoshikawa, M ;
Bandow, S .
PHYSICAL REVIEW B, 1998, 58 (24) :16387-16395
[2]   Graphene-based liquid crystal device [J].
Blake, Peter ;
Brimicombe, Paul D. ;
Nair, Rahul R. ;
Booth, Tim J. ;
Jiang, Da ;
Schedin, Fred ;
Ponomarenko, Leonid A. ;
Morozov, Sergey V. ;
Gleeson, Helen F. ;
Hill, Ernie W. ;
Geim, Andre K. ;
Novoselov, Kostya S. .
NANO LETTERS, 2008, 8 (06) :1704-1708
[3]   Substrate-free gas-phase synthesis of graphene sheets [J].
Dato, Albert ;
Radmilovic, Velimir ;
Lee, Zonghoon ;
Phillips, Jonathan ;
Frenklach, Michael .
NANO LETTERS, 2008, 8 (07) :2012-2016
[4]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[5]   Uptake of H2 and CO2 by graphene [J].
Ghosh, Anupama ;
Subrahmanyam, K. S. ;
Krishna, Katia Sai ;
Datta, Sudipta ;
Govindaraj, A. ;
Pati, Swapan K. ;
Rao, C. N. R. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (40) :15704-15707
[6]   Energy band-gap engineering of graphene nanoribbons [J].
Han, Melinda Y. ;
Oezyilmaz, Barbaros ;
Zhang, Yuanbo ;
Kim, Philip .
PHYSICAL REVIEW LETTERS, 2007, 98 (20)
[7]   High-yield production of graphene by liquid-phase exfoliation of graphite [J].
Hernandez, Yenny ;
Nicolosi, Valeria ;
Lotya, Mustafa ;
Blighe, Fiona M. ;
Sun, Zhenyu ;
De, Sukanta ;
McGovern, I. T. ;
Holland, Brendan ;
Byrne, Michele ;
Gun'ko, Yurii K. ;
Boland, John J. ;
Niraj, Peter ;
Duesberg, Georg ;
Krishnamurthy, Satheesh ;
Goodhue, Robbie ;
Hutchison, John ;
Scardaci, Vittorio ;
Ferrari, Andrea C. ;
Coleman, Jonathan N. .
NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568
[8]   Graphene: carbon in two dimensions [J].
Katsnelson, Mikhail I. .
MATERIALS TODAY, 2007, 10 (1-2) :20-27
[9]   Measurement of the elastic properties and intrinsic strength of monolayer graphene [J].
Lee, Changgu ;
Wei, Xiaoding ;
Kysar, Jeffrey W. ;
Hone, James .
SCIENCE, 2008, 321 (5887) :385-388
[10]   Room-temperature quantum hall effect in graphene [J].
Novoselov, K. S. ;
Jiang, Z. ;
Zhang, Y. ;
Morozov, S. V. ;
Stormer, H. L. ;
Zeitler, U. ;
Maan, J. C. ;
Boebinger, G. S. ;
Kim, P. ;
Geim, A. K. .
SCIENCE, 2007, 315 (5817) :1379-1379