Substrate-free gas-phase synthesis of graphene sheets

被引：637

作者：

Dato, Albert ^{[1
]}

Radmilovic, Velimir ^{[2
]}

Lee, Zonghoon ^{[2
]}

Phillips, Jonathan ^{[3
]}

Frenklach, Michael ^{[4
]}

机构：

[1] Univ Calif Berkeley, Appl Sci & Technol Grad Grp, Berkeley, CA 94720 USA

[2] Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA

[3] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[4] Univ Calif Berkeley, Dept Mech Engn, Berkeley, CA 94720 USA

来源：

NANO LETTERS | 2008年 / 8卷 / 07期

关键词：

D O I：

10.1021/nl8011566

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a novel method for synthesizing graphene sheets in the gas phase using a substrate-free, atmospheric-pressure microwave plasma reactor. Graphene sheets were synthesized by passing liquid ethanol droplets into an argon plasma. The graphene sheets were characterized by transmission electron microscopy, electron energy loss spectroscopy, Raman spectroscopy, and electron diffraction. We prove that graphene can be created without three-dimensional materials or substrates and demonstrate a possible avenue to the large-scale synthesis of graphene.

引用

页码：2012 / 2016

页数：5

共 33 条

[1] Electronic confinement and coherence in patterned epitaxial graphene
Berger, Claire
Song, Zhimin
Li, Xuebin
Wu, Xiaosong
Brown, Nate
Naud, Cecile
Mayou, Didier
Li, Tianbo
Hass, Joanna
Marchenkov, Atexei N.
Conrad, Edward H.
First, Phillip N.
de Heer, Wait A.
[J]. SCIENCE, 2006, 312 (5777) : 1191 - 1196
[2] EELS ANALYSIS OF VACUUM ARC-DEPOSITED DIAMOND-LIKE FILMS
BERGER, SD
MCKENZIE, DR
MARTIN, PJ
[J]. PHILOSOPHICAL MAGAZINE LETTERS, 1988, 57 (06) : 285 - 290
[3] Raman fingerprint of charged impurities in graphene
Casiraghi, C.
Pisana, S.
Novoselov, K. S.
Geim, A. K.
Ferrari, A. C.
[J]. APPLIED PHYSICS LETTERS, 2007, 91 (23)
[4] Characterization of amorphous and nanocrystalline carbon films
Chu, PK
Li, LH
[J]. MATERIALS CHEMISTRY AND PHYSICS, 2006, 96 (2-3) : 253 - 277
[5] Three-dimensional carbon nanowall structures
Chuang, Alfred T. H.
Robertson, John
Boskovic, Bojan O.
Koziol, Krzysztof K. K.
[J]. APPLIED PHYSICS LETTERS, 2007, 90 (12)
[6] Freestanding carbon nanowalls by microwave plasma-enhanced chemical vapour deposition
Chuang, Alfred T. H.
Boskovic, Bojan O.
Robertson, John
[J]. DIAMOND AND RELATED MATERIALS, 2006, 15 (4-8) : 1103 - 1106
[7] Structural coherency of graphene on Ir(111)
Coraux, Johann
N'Diaye, Alpha T.
Busse, Carsten
Michely, Thomas
[J]. NANO LETTERS, 2008, 8 (02) : 565 - 570
[8] Study of different forms of carbon by analytical electron microscopy
Duarte-Moller, A
Espinosa-Magaña, F
Martínez-Sanchez, R
Avalos-Borja, M
Hirata, GA
Cota-Araiza, L
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1999, 104 (1-3) : 61 - 66
[9] Raman spectrum of graphene and graphene layers
Ferrari, A. C.
Meyer, J. C.
Scardaci, V.
Casiraghi, C.
Lazzeri, M.
Mauri, F.
Piscanec, S.
Jiang, D.
Novoselov, K. S.
Roth, S.
Geim, A. K.
[J]. PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[10] Raman spectroscopy of graphene and graphite: Disorder, electron-phonon coupling, doping and nonadiabatic effects
Ferrari, Andrea C.
[J]. SOLID STATE COMMUNICATIONS, 2007, 143 (1-2) : 47 - 57

← 1 2 3 4 →