Regio- and Stereoselective Au(I)-Catalyzed Intermolecular Hydroalkoxylation of Aryl Allenes

被引：33

作者：

Cui, Dong-Mei ^{[1
]}

Yu, Ke-Rui ^{[1
]}

Zhang, Chen ^{[2
]}

机构：

[1] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China

[2] Zhejiang Univ, Sch Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China

来源：

SYNLETT | 2009年 / 07期

关键词：

allenes; catalysis; alcohols; regioselectivity; stereoselectivity; hydroalkoxylation; GOLD-CATALYZED CYCLOISOMERIZATION; HIGHLY EFFICIENT; ALPHA-HYDROXYALLENES; ALKYNES; CYCLIZATION; GOLD(III); ALCOHOLS; ACIDS; 2,5-DIHYDROFURANS; HYDROAMINATION;

D O I：

10.1055/s-0028-1088158

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a catalytic amount of Ph3PAuNO3 and H2SO4, the hydroalkoxylation of allenes with alcohols has been shown to proceed smoothly and give allylic ethers in good yields and high regio- and stereoselectivity.

引用

页码：1103 / 1106

页数：4

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