EU-wide survey of polar organic persistent pollutants in European river waters

被引:776
作者
Loos, Robert [1 ]
Gawlik, Bernd Manfred [1 ]
Locoro, Giovanni [1 ]
Rimaviciute, Erika [1 ]
Contini, Serafino [1 ]
Bidoglio, Giovanni [1 ]
机构
[1] Commiss European Communities, Joint Res Ctr, Inst Environm & Sustainablility, I-21020 Ispra, Italy
关键词
River waters; EU-wide monitoring; SPE-LC-MS(2); TANDEM MASS-SPECTROMETRY; MUNICIPAL WASTE-WATER; SURFACE WATERS; PERFLUOROOCTANOATE PFOA; ENVIRONMENTAL-SAMPLES; PERFLUORINATED ACIDS; AQUATIC ENVIRONMENT; PHARMACEUTICALS; PESTICIDES; SPAIN;
D O I
10.1016/j.envpol.2008.09.020
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study provides the first EU-wide reconnaissance of the occurrence of polar organic persistent pollutants in European river waters. More than 100 individual water samples from over 100 European rivers from 27 European Countries were analysed for 35 selected compounds, comprising pharmaceuticals, pesticides, PFOS, PFOA, benzotriazoles, hormones, and endocrine disrupters. Around 40 laboratories participated in this sampling exercise. The most frequently and at the highest concentration levels detected compounds were benzotriazole, caffeine, carbamazepine, tolyltriazole, and nonylphenoxy acetic acid (NPE(1)C). Only about 10% of the river water samples analysed could be classified as "very clean" in terms of chemical pollution. The rivers responsible for the major aqueous emissions of PFOS and PFOA from the European Continent could be identified. For the target compounds chosen, we are proposing "indicative warning levels" in surface waters, which are (for most compounds) close to the 90th percentile of all water samples analysed. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:561 / 568
页数:8
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