Triplet state of WUrster's blue-based di(cation radical)

被引:32
作者
Ito, A [1 ]
Taniguchi, A [1 ]
Yamabe, T [1 ]
Tanaka, K [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Sakyo Ku, Kyoto 6068501, Japan
关键词
D O I
10.1021/ol990727w
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] N,N'-bis[4-(dimethylamino)phenyl] N,N-dimethyl-1,3-benzenediamine was prepared in order to investigate the corresponding Wurster blue-based di(cation radical). The generated diradical was found to be aground-state triplet, and moreover, the observed ESR spectrum had no definite fine structure, suggesting a mixture of some conformers.
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页码:741 / 743
页数:3
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