Corn-shape carbon nanofibers (CCNFs) with metal-free tips have been synthesized by a microwave plasma-enhanced chemical-vapor deposition method using CH4 and H-2 gasses. The CCNFs were grown on Ni/SiO2/Si and Ni/Mo mesh substrates using a bias-enhanced growth method, and they were analyzed by scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. The cones are composed of cylindrical pure graphite sheets, and have nanometer-sized tips and roots. The tips' apex angles of CCNFs have cone angles of 20degrees, 39degrees, and 60degrees depending on the growth conditions such as substrate temperature. (C) 2004 American Institute of Physics.