Magnesium hydroxide and microencapsulated red phosphorus synergistic flame retardant form stable phase change materials based on HDPE/EVA/OMT nanocomposites/paraffin compounds

被引：25

作者：

Cai, Y. B. ^{[1
,2
]}

Wei, Q. F. ^{[1
]}

Shao, D. F. ^{[1
]}

Hu, Y. ^{[2
]}

Song, L. ^{[2
]}

Gao, W. D. ^{[1
]}

机构：

[1] Jiangnan Univ, Key Lab Ecotext, Minist Educ, Wuxi 214122, Peoples R China

[2] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Peoples R China

来源：

JOURNAL OF THE ENERGY INSTITUTE | 2009年 / 82卷 / 01期

关键词：

Phase change materials; Organophilic montmorillonite; Thermal stability; Thermal oxidative degradation; Latent heat; Flammability; Synergistic effect; HALOGEN; STORAGE; FIRE; CLAY; POLYPROPYLENE; FLAMMABILITY; COMBUSTION; POLYMER; POLYETHYLENE; POLYAMIDE-6;

D O I：

10.1179/014426008X370988

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The flame retardant form stable phase change materials (PCM) based on high density polyethylene (HDPE)/ethylene-vinyl acetate (EVA)/organophilic montmorillonite (OMT) nanocomposites and paraffin compounds were prepared. The flame retardant system used consisted of magnesium hydroxide (MH) and microencapsulated red phosphorus (MRP). The structures and properties of the form stable PCM composites were respectively characterised by X-ray diffraction (XRD), scanning electronic microscope (SEM), thermogravimetry analysis (TGA), differential scanning calorimeter (DSC) and cone calorimeter. The XRD and SEM results showed the paraffin dispersed in the three-dimensional net structure formed by HDPE-EVA/OMT nanocomposites. The TGA results indicated that the loading of the MH/MRP and OMT improved the thermal stability and thermal oxidative degradation properties of the form stable PCM composites. The DSC measurements indicated that the additives of flame retardant and OMT had little effect on the thermal energy storage properties. It was also found from the cone calorimeter tests that the peak of heat release rate (PHRR) decreased significantly. Both the decrease in the PHRR and compact and homogeneous charred residue after combustion indicated that there was a synergistic effect among the MH, MRP and OMT, contributing to the improved thermal and flammability properties of the form stable PCM composites.

引用

页码：28 / 36

页数：9

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